Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination.
نویسندگان
چکیده
The cooperative catalysis of CpRu(PPh3)2(CH3CN)PF6 (1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding beta-hydroxynitriles in good yield.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 28 شماره
صفحات -
تاریخ انتشار 2005